Mike said:
Not sure I can go with this one Matt. Cars do not have a means of depleting
air from the gas tank. They have the means to control the pressure in the
tank relative to atmospheric pressure, but not the gases that make up that
pressure. There is no way to remove the oxygen (even the levels typical of
the air we breath) in a gas tank, thus oxidation is not only possible in a
metal gas tank, but common.
I'm not so sure though, how much of a problem oxidation from within the tank
really is though. I believe more of the issues with contaminants inside the
tank are from those contaminants being pumped into the tank at the gas
station.
I can't find a reference at the moment, but I remember reading that one
reason that there isn't an explosion concern with in-tank electric fuel
pumps is that the tank has only liquid gasoline and gasoline vapor and
not enough oxygen to support combustion or explosion. The explanation
was that the charcoal canister traps excess gasoline vapor which is them
drawn back into the tank as the fuel is depleted. Proper operation of
this system requires the gas cap to be tightly in place hence the fact
that most modern cars (I think OBD II and later) will light the MIL
indicator.
And, as I've mentioned previously, I run my cars down to 1/8 tank (until
the light comes on) quite often and I've never had a tank rust out and
have had only one electric fuel pump fail and that was after about
150,000 miles so I don't think it was a failure due to overheating of
the pump due to lack of gas in the tank as that would happen much sooner
than 9 years and 150K miles.
Matt